Flammability limit

Mixtures of dispersed combustible materials (such as gaseous or vaporised fuels, and some dusts) and oxygen in the air will burn only if the fuel concentration lies within well-defined lower and upper bounds determined experimentally, referred to as flammability limits or explosive limits. Combustion can range in violence from deflagration through detonation.

Limits vary with temperature and pressure, but are normally expressed in terms of volume percentage at 25 °C and atmospheric pressure. These limits are relevant both in producing and optimising explosion or combustion, as in an engine, or to preventing it, as in uncontrolled explosions of build-ups of combustible gas or dust. Attaining the best combustible or explosive mixture of a fuel and air (the stoichiometric proportion) is important in internal combustion engines such as gasoline or diesel engines.

The standard reference work is still that elaborated by Michael George Zabetakis, a fire safety engineering specialist, using an apparatus developed by the United States Bureau of Mines.